Correct set of species which have zero dipole moment

C O_{2} - B C l_{3}

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C O C l_{2} - B C l_{3}

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C H_{2} C l_{2} - B C l_{3}

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C O_{2} - C H_{2} C l_{2} - B C l_{3}

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Solution

The correct option is A $C O_{2} - B C l_{3}$
$C O_{2}$ is linear and $C C l_{4}$ is trigonal planar hence net polarity of both molecules is zero. On the other hand, $C O C l_{2}$ and $C H 2 C l_{2}$ are polar molecules and hence will have a non-zero dipole moment.

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