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Question

Corrosive sublimate (HgCl2) can be used to distinguish between:

A
formaldehyde and propanone
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B
formic acid and acetic acid
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C
acetaldehyde and butanone
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D
all of the above
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Solution

The correct option is A formic acid and acetic acid
Option B is the correct answer.
Formic acid gives white precipitate with HgCl2 but acitic acid does not react.
HCO2H+2HgCl2Hg2Cl2white precipitate+2HCl+CO2
CH3COOHHgCl2−−− No precipitate of Hg2Cl2
Formic acid acts as a reducing agent.

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