The correct option is B [Ne]3s2,3p6,3d5,4s1
Cr has atomic number of 24. It;s electronic configuration hence is expected to be [Ar]3d44s2 but it is observed to be [Ar]3d54s1. This is because 3d5 is half filled and thus provides more stability. Thus configuration of Cr is [Ar]3d54s1 or [Ne]3s23p63d54s1