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Question

CsBr crystallises in a body centred cubic lattice. the unit cell length is 436.6 pm . given that the atomic mass of Cs = 133 and that of Br= 80 amu, what will be the density of CsBr?

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Solution

CsBr is a bcc lattice. So no of particles in bcc (Z) = 2Density,ρ = Z × Ma3 × NAWhere Z = no of particles = 2M = molecular mass = 133 + 80 = 213 ga = 436.6 pm = 436.6 × 10-10 cmNA = avogadro number = 6.022 × 1023Density,ρ = Z × Ma3 × NA = 2 × 213436.6 × 10-103 × 6.022 × 1023 = 8.499 g/cm3

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