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Question

CsOH+HClCsCl+H2O;ΔH=13.4Kcalmol1....(i)
CsOH+HFCsF+H2O;ΔH=16.4Kcalmol1....(ii)
Calculate ΔH for the ionisation of HF in H2O

A
ΔH=3.0Kcal
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B
ΔH=+3.0Kcal
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C
ΔH=29.7.0Kcal
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D
None of these
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Solution

The correct option is C ΔH=3.0Kcal
Sol. The ionisation of HF is as shown.
HFH+F....ΔH=?

The neutralisation of CsOH with HCl is as shown
CsOH+HClCsCl+H2O or

OH(Strong base)+H(acid)H2O.....ΔH2=13.4Kcal ......(i)

The neutralisation of CsOH with HF is as shown.
OH(Strong base)+HF(Weak acid)H2O....ΔH2=16.4Kcal ......(ii)

The enthalpy change for the ionisation of HF is
ΔH=ΔH2ΔH1 =16.4(13.4)

=3.0Kcal

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