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Question

CuSO4 when reacts KCN forms x, which is insoluble in water. x is soluble in excess of KCN, due to formation of :

A
K2[Cu(CN)4]
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B
K3[Cu(CN)4]
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C
CuCN2
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D
Cu[KCu(CN)4]
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Solution

The correct option is A K3[Cu(CN)4]
Option (B) is correct.
CuSO4 when reacts KCN forms CuCN,which is insoluble in water.

CuCN is soluble in excess of KCN, due to formation of K3[Cu(CN)4].
CuSO4 when reacts KCN forms a white precipitate of cuprous cyanide and cyanogen gas. The cuprous cyanide dissolves in excess of KCN, due to formation of K3[Cu(CN)4].

CuSO4 + 2KCN Cu(CN)2 + K2SO4

2Cu(CN)2 2CuCN +CNCN

CuCN +3KCN K3[Cu(CN)4]

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