CuSO4 when reacts KCN forms x, which is insoluble in water. x is soluble in excess of KCN, due to formation of:
A
K2[Cu(CN)4]
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B
K3[Cu(CN)4]
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C
CuCN2
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D
Cu[KCu(CN)4]
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Solution
The correct option is AK3[Cu(CN)4] Option (B) is correct. CuSO4 when reacts KCN forms CuCN,which is insoluble in water.
CuCN is soluble in excess of KCN, due to formation of K3[Cu(CN)4]. CuSO4 when reacts KCN forms a white precipitate of cuprous cyanide and cyanogen gas. The cuprous cyanide dissolves in excess of KCN, due to formation of K3[Cu(CN)4].