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Question

Cyanide ion acts as an ambiant nucleophile.From which end it acts as a stronger nuclephile in aquaous medium.

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Solution

Cyanide ion is an ambidentate ion. i.e., it acts as CN- and NC-In aqueous solution CN- is a stronger nucleophile because here the carbon end leads to the formation of stable C-C bond, whereas the C-N bond is less stable.Another reason is CN- is a strong nucleophile and strong base becuase itsconjucate acid (HCN) is a weak acid.

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