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Question

Cyclobutadiene is said to be :

A
aromatic
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B
aliphatic
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C
anti-aromatic
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D
none of the above
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Solution

The correct option is C anti-aromatic
According to Huckel's rule, if a cyclic, planar molecule has (4n+2) π electrons, it is considered to be aromatic.

Aliphatic compounds are chemical compounds belonging to the organic class in which the atoms are not linked together to form a ring. They are non-aromatic compounds.

Antiaromaticity is a characteristic of a cyclic molecule with a π electron system that has higher energy due to the presence of 4nπ electrons in it.

Unlike aromatic compounds, which follow Hückel's rule ([4n+2]π electrons) and are highly stable, antiaromatic compounds are highly unstable and highly reactive.

So, cyclobutadiene is anti-aromatic as it has 4π electrons. (Cyclic, planar)

Option C is correct.

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