The correct option is D PCl5
Dative bond is present in the PCl5 molecule.
In the solid state, PCl5 molecule exists in the form of [PCl4]+ [PCl6]−
Dative bond is present in [PCl6]− ion. The chloride ion is the donor atom and P atom is acceptor atom. The dative bond is also called co-ordinate covalent bond.