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Question

Decarboxylation occurs with maximum rate in:

A
CH3COOH
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B
C6H5COOH
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C
C6H5CH2COOH
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D
CH3COCH2COOH
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Solution

The correct option is C CH3COCH2COOH
The correct option is D. CH3COCH2COOH is a β-keto acid. Thus decarboxylation is maximum in a carboxylic acid containing an electron withdrawing group such as =CO or COOH at the β-carbon atom with respect to the COOH group.

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