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Byju's Answer
Standard XII
Chemistry
First Order Reaction
Decomposition...
Question
Decomposition of nitrogen pentoxide
N
2
O
5
in
C
C
l
4
is a ______ reaction
A
Sequential
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B
First order
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C
Pseudo first order
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D
Parallel
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Solution
The correct option is
B
First order
Decomposition of
N
2
O
5
to
N
O
2
and
O
2
in
C
C
l
4
solution is a first order reaction.
N
2
O
5
→
2
N
O
2
+
1
2
O
2
The rate of the reaction of decomposition of
N
2
O
5
is proportional to its concentration as follows -
−
d
[
N
2
O
5
]
d
t
=
k
[
N
2
O
5
]
where k is the rate constant.
So, the correct option is (B).
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0
Similar questions
Q.
The decomposition of dinitrogen pentoxide
(
N
2
O
5
)
follows first order rate law. Calculate the rate constant from the given data:
t
=
800
sec
[
N
2
O
5
]
=
1.45
m
o
l
L
−
1
=
[
A
1
]
t
=
1600
sec
[
N
2
O
5
]
=
0.88
m
o
l
L
−
1
=
[
A
2
]
Q.
The reaction
N
2
O
5
(in
C
C
l
4
)
→
2
N
O
2
+
1
/
2
O
2
(
g
)
is first order in
N
2
O
5
with rate constant
6.2
×
10
−
4
. What is the value of rate of reaction when
[
N
2
O
5
]
=
1.25
m
o
l
e
L
−
1
Q.
For a first order reaction involving decomposition of
N
2
O
5
, the following information is available :
2
N
2
O
5
(
g
)
→
4
N
O
2
(
g
)
+
O
2
(
g
)
Rate = k
[
N
2
O
5
]
N
2
O
5
(g)
→
2
N
O
2
(g) +
1
2
O
2
(g) Rate =
k
′
[
N
2
O
5
]
,
Which of the following expressions is true ?
Q.
The decomposition of
N
2
O
5
in
C
C
l
4
solution at 320 K takes place as
2
N
2
O
5
→
4
N
O
2
+
O
2
; On the bases of given data order and the rate constant of the reaction is :
T
i
m
e
i
n
m
i
n
u
t
e
s
10
15
20
25
∞
V
o
l
u
m
e
o
f
O
2
6.30
8.95
11.40
13.50
34.75
e
v
o
l
v
e
d
(
i
n
m
L
)
Q.
The half life decomposition of
N
2
O
5
in a first order reaction represented by
N
2
O
5
→
N
2
O
4
+
1
2
O
2
After 20 min the volume of
O
2
produced is 10 ml and at the end of the reaction 40 ml. The value of rate constant is:
[
G
i
v
e
n
2.303
log
(
4
3
)
=
0.28
]
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