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Question

Decreasing order of acidic strength of different (-OH) group is:
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A
w>x>y>z
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B
w>z>x>y
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C
z>w>x>y
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D
z>x>w>y
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Solution

The correct option is A w>x>y>z
w will be the most acidic, as the anion (formed after the proton is removed) is stabilized by resonance in benzene ring.
z will be the least acidic as the anion formed will experience a significant +I effect from the CH2 group adjacent to it, thus destabilizing it.
x will be comparatively more acidic than y as it experiences less +I effect to a less extent. Hence the order of acidic strength is:
w>x>y>z

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