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Standard XII

Chemistry

Assigning Oxidation Numbers

Deduce the st...

Question

Deduce the structural formula of a compound (A) $(C_{10} H_{16})$ that gives (B) as the only compound on oxidation with acidic $K M n O_{4}$ .

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Solution

The structure A is following :

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Similar questions

Q. Deduce the structural formula of a compound,

C_{10} H_{10} (A)

that gives

(B)

on oxidation:

H O O C (B) - C H_{2} - C | C H_{2} - C O O H H - C H_{2} - C O O H

Q. A neutral organic compound A has formula

C_{9} H_{16} O_{3}

and rotates plane polarized light. A on acid hydrolysis produces B and

C (C_{3} H_{8} O)

. C on partial oxidation with PCC gives

D (C_{3} H_{6} O)

which does not give iodoform test. D on treatment with dilute solution of

N a O H

gives

E (C_{6} H_{12} O_{2})

which is diastereomeric. E on treatment with the acidic solution of

K M n O_{4}

produces B. Deduce structures of A to E.

Q. An organic compound

A (C_{6} H_{10})

on reduction first gives

B (C_{6} H_{12})

and finally

C (C_{6} H_{14})

. Compound

A

on ozonolysis followed by hydrolysis gives two aldehydes

D (C_{2} H_{4} O)

and

E (C_{2} H_{2 -} O_{2})

. Oxidation of

B

with acidified

K M n O_{4}

gives the acid

F (C_{4} H_{8} O_{2})

. Determine the structures of the compounds

A

F

with reasoning.

Q. An organic compound A of molecular formula

C_{2} H_{6} O

on oxidation gives an acid B with the same number of carbon atom as A. Compound A is also used in preparation of tincture iodine.
Select the correct structure of compounds A and B respectively.

Q. An ether

A

(C_{5} H_{12} O)

when heated with excess of hot concentrated

H I

produced two alkyl halides which on hydrolysis from compounds

B

and

C

. Oxidation of

B

gives an acid

D

whereas oxidation of

C

gave a ketone

E

. Deduce the structures of

A, B, C, D

and

E

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Deduce the structural formula of a compound (A) (C10H16) that gives (B) as the only compound on oxidation with acidic KMnO4.

The structure A is following :

Deduce the structural formula of a compound (A) $(C_{10} H_{16})$ that gives (B) as the only compound on oxidation with acidic $K M n O_{4}$ .