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Define absolute zero

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Solution

Absolute zero is defined as the point where no more heat can be removed from a system, according to the absolute or thermodynamic temperature scale. This corresponds to 0 K or -273.15°C. This is 0 on the Rankine scale and -459.67°F.

In classical kinetic theory, there should be no movement of individual molecules at absolute zero, but experimental evidence shows this isn't the case. Rather, particles at absolute zero have minimal vibrational motion.

In other words, while heat may not be removed from a system at absolute zero, it does not represent the lowest possible enthalpy state.

In quantum mechanics, absolute zero refers to the lowest internal energy of solid matter in its ground state.

Robert Boyle was among the first people to discuss the existence of an absolute minimum temperature in his 1665 New Experiments and Observations Touching Cold. The concept was called the primum frigidum.

Absolute Zero and Temperature

Temperature is used to describe how hot or cold an object it. The temperature of an object depends on how fast its atoms and molecules oscillate. At absolute zero, these oscillations are the slowest they can possibly be. Even at absolute zero, the motion doesn't completely stop.

Can We Reach Absolute Zero?

It's not possible to reach absolute zero, though scientists have approached it. The NIST achieved a record cold temperature of 700 nK (billionths of a Kelvin) in 1994.

MIT researchers set a new record of 0.45 nK in 2003.

Negative Temperatures

Physicists have shown that it's possible to have a negative Kelvin (or Rankine) temperature. However, this doesn't mean particles are colder than absolute zero, but that energy has decreased. This is because temperature is a thermodynamic quantity that relates energy and entropy.


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