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Question

Define exothermic and endothermic changes. Give two examples in each case.

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Solution

When a chemical reaction occurs, energy is transferred to, or from, the surroundings - and there is often a temperature change. For example, when a bonfire burns it transfers heat energy to the surroundings. Objects near a bonfire become warmer. The temperature rise can be measured with a thermometer.

Exothermic reactions

These are reactions that transfer energy to the surroundings. The energy is usually transferred as heat energy, causing the reaction mixture and its surroundings to become hotter. The temperature increase can be detected using a thermometer. Some examples of exothermic reactions are:

  • burning
  • Neutralization reactions between acids and alkalis
  • the reaction between water and calcium oxide

Endothermic reactions

These are reactions that take in energy from the surroundings. The energy is usually transferred as heat energy, causing the reaction mixture and its surroundings to get colder. The temperature decrease can also be detected using a thermometer. Some examples of endothermic reactions are:

  • electrolysis
  • the reaction between ethanoic acid and sodium carbonate
  • the thermal decomposition of calcium carbonate in a blast furnace

The animation shows an exothermic reaction between sodium hydroxide and hydrochloric acid, and an endothermic reaction between sodium carbonate and ethanoic acid.

Exothermic processes Endothermic processes
making ice cubes melting ice cubes
formation of snow in clouds conversion of frost to water vapor
condensation of rain from water vapor evaporation of water
a candle flame forming a cation from an atom in the gas phase
mixing sodium sulfite and bleach baking bread
rusting iron cooking an egg
burning sugar producing sugar by photosynthesis
forming ion pairs separating ion pairs
Combining atoms to make a molecule in the gas phase splitting a gas molecule apart
mixing water and strong acids mixing water and ammonium nitrate
mixing water with an anhydrous salt making an anhydrous salt from a hydrate
crystallizing liquid salts (as in sodium acetate in chemical handwarmers) melting solid salts
nuclear fission reaction of barium hydroxide octahydrate crystals with dry ammonium chloride
mixing water with calcium chloride reaction of thionyl chloride (SOCl2) with cobalt(II) sulfate heptahydrate

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