London dispersion forces:
→Weakest intermolecular forces
→Temporary attractive forces that results when the electron in 2 adjacent atoms occupy positions that make atoms form temporary dipoles.
→Also know as induced dipole-induced dipole attraction or instantaneous dipole induced dipole forces.
→These forces cause non-polar substances to condense to liquids and to freeze to solids, when temperature is lowered sufficiently.
→Exist in molecules such as F2,O2,N2 and even in mono-atomic molecules He,Ne,Ar etc.
→Electron of a neutral molecule keep on oscillating with respect to nuclei of atoms. As a result at an instant, positive charge may concentrate in one region and negative charge in another region in same molecule causing 'self-polarization' of molecule.
→This polarized molecule may induce a dipole moment in a neighboring molecule
(Image 1)
→Second atom can be distorted by appearance of dipole in first atom or molecule resulting to electrostatic attraction between 2 atoms or molecule.
(Image 2)