Order of a reaction: It is defined as sum of the powers to which the concentration (or pressure) terms are raised in the rate-law expression. The order of a reaction is an experimental quantity.
The order of a reaction, in general, may or may not be numerically equal to a+b+c for a general reaction of type,
Example:aA+bB+cC⟶lL+mM+pP
Rate of reaction of this reaction is given by
Rate= K[A]x[B]y[C]z
where, x,y,z are order of reaction with respect to the reactants A,B,C.
Overall order of the reaction is given by x+y+z.