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Question

Define water of crystallization? Give the chemical formula for two compounds as examples? How can it be proved that the water of crystallization makes a difference in the state and color of the compounds?


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Solution

The water of crystallization:

  • It is the fixed number of water molecules present in one formula unit of salt.

For examples:

CuSO4.5H2O (Copper sulfate Penta hydrate) Blue vitriol.
FeSO4.7H2O (Ferrous sulfate heptahydrate) Green vitriol.

  • By heating these salts they lose their water molecules and hence result in a change in state and color taking place.
  • Blue vitriol is blue as it contains 5 molecules of water of crystallization.
  • When it is heated, it loses water of crystallisation and becomes anhydrous copper sulfate (CuSO4) which is grey-white.
  • On heating green vitriol, anhydrous ferrous sulfate (FeSO4) is formed, which is white.
  • Anhydrous ferrous sulfate (FeSO4) on further heating, decomposes into ferric oxide (Fe2O3), Sulfur dioxide (SO2), and sulfur trioxide (SO3) gas is released.

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