Dehydration of ammonium carbamate produces:
The ability of ammonium carbamate to make urea was first discovered in 1870 by Bassarov when he heated ammonium carbamate in sealed glass tubes at temperatures ranging from 130 to 140 ℃. This yields urea and water in an equimolar ratio. A typical industrial plant that makes urea can produce up to 1500 tons a day. Ammonia and carbon dioxide is excessively fed to a synthesis reactor in this process. Ammonium carbamate is produced as an intermediate in this reactor and can then be dehydrated to urea according to the following equation.
H2N−COONH4→NH2CONH2+H2O