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Question

Δ x is given by: Δx = (hydration energy) - (lattice energy). For a salt, Δx is found to be 500 k cal mol1. Then on increasing the temperature, its solubility in water


A
increases
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B
decreases
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C
remains same
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D
increases initially and then decreases
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Solution

The correct option is B decreases
ΔHSolution= Lattice Energy - hydration energy
So, ΔHSolution is - ve for given process
When ΔHSolution is - ve solubility decreases with increase in temperature

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