Δ x is given by: Δx = (hydration energy) - (lattice energy). For a salt, Δx is found to be 500 k cal mol−1. Then on increasing the temperature, its solubility in water
A
increases
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B
decreases
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C
remains same
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D
increases initially and then decreases
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Solution
The correct option is B decreases ΔHSolution= Lattice Energy - hydration energy So, ΔHSolution is - ve for given process When ΔHSolution is - ve solubility decreases with increase in temperature