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Question

Derive expression for the ratio of specific heats γ if the gas has f degrees of freedom.

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Solution

The molar specific heats of a gas having f degrees of freedom is given by :
Cv=12fR
and Cp=Cv+R [From 1st law of thermodynamic ]
Cp=(f2+1)R
(f+2)2R.
Thus ratio, r=CpCv=(f+2)R2×2fR=f+2f

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