Let a parallel plate capacitor be applied a voltage V across its terminals due to which a charge Q develops across its ends.
Separation between plates is d and area of plates is A.
From gauss's theorem one can show electric field inside the capaciton plates Q,
E=σϵo, where σ=QA (charge / Area)
⇒E=QAϵo
Now, voltage across the plates is related by :
V=Ed [In general , dV=−→E.d→r but we take as →E is uniform]
⇒V=QdAϵo⇒QV=Aϵod
Now, capacitance is defined by C=QV, thus we get :-
C=Aϵod