The potentiometer is a device used to compare the e.m.f of two cells. It works on the principle that when a constant current flows through a wire of uniform cross-sectional area, a potential difference between its two points, is directly proportional to the length of the wire between the two points.
Construction: It consists of a long uniform cross-sectional area and of 10m in length. The material of the wire should have a high resistivity and low-temperature coefficient. The wires are joined in series by using thick copper strips. A matter scale is also attached to the wooden board.
Comparing E.m.f of two cells:
Using a potentiometer, we can determine the e.m.f of a cell by obtaining the balancing length l of the potentiometer wire is equal to the e.m.f of the cell, as no current is being drawn from the cell, Then,
Eαl
or E=kl {k:Potentialgradient}
For comparing e.m.f of two cells,
E1E2=kl1kl2=l1l2