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Question

Describe the preparation of potessium permangnate. How does the acidilified permangnanate solution react with
(i) irons
(ii) SO2
Write the ionic equations for the reactions.

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Solution

Preparation of Potassium Permanganate,
3K2MnO4+2CO22KMnO4+MnO2+2K2CO3
Potassium Manganate is oxidized to Potassium Permanganate by bubbling CO2 or Cl2 or O3 into the former.
Ionic equations of the following reactions:
(i)KMnO4 with Fe:
2MnO42+16H++10Fe2+2Mn2++8H2O+10Fe3+
(ii)KMnO4 with SO2:
2MnO4+5SO2+H2O5SO42+2Mn2++4H+

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