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Question

Determine the simplest formula of an ionic compound in which cations are present at the corners and the anions occur at the center of each face.

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Solution

Let cations be A. There are 8 corners. Contribution of eah corner is 18. Total A atom is 18×8=1.
Let anions be B. There are 6 faces. Contribution of each phase is 12. Total B atom is 12×6=3.
Formula is AB3.

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