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Question

Determine the unknown solute from the given observation.
"An unknown solution (pH of 3.5) was titrated with 0.1 M NaOH, which gives a single equivalence point at pH 7 on titration curve."

A
HF
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B
HCl
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C
LiOH
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D
NH3
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E
H2SO4
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Solution

The correct option is A HCl
Since the pH of unknown solute is less than 7, it is an acid.
During titration, a single equivalence point at pH 7 on titration curve is obtained which is characteristic of the titration of strong acid with strong base.
Hence, the unknown solute is HCl, a strong acid.

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