Determine which of the following reactions taking place at constant pressure represents a system that does work on the surrounding environment. I. Ag+(aq)+Cl−(aq)→AgCl(s)
II.NH4Cl(s)→NH3(g)+HCl(g) III. 2NH3(g)→N2(g)+3H2(g)
A
I
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B
III
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C
II and III
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D
I and II
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Solution
The correct option is A I In equation Ag+(ag)+Cl(ag)⟶AgCl(5).
No species is in gaseous state, so the reaction will take place at constant pressure.