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Question

Diethyl ether and air gives ether-hydroperoxide. The mechanism of the reaction is:

A
Nucleophilic substitution
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B
Free radical addition
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C
Free radical substitution
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D
None of the above
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Solution

The correct option is B Free radical addition
Diethyl ether hydroperoxide can be formed by the reaction of oxygen with diethyl ether. This is a free radical addition reaction, carried out by UV excitation of molecular oxygen into a more reactive form.
Hence correct option is B

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