Diethyl ether and air gives ether-hydroperoxide. The mechanism of the reaction is:
A
Nucleophilic substitution
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B
Free radical addition
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C
Free radical substitution
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D
None of the above
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Solution
The correct option is B Free radical addition Diethyl ether hydroperoxide can be formedby the reaction of oxygen with diethyl ether. This is a free radical addition reaction, carried out by UV excitation of molecular oxygen into a more reactive form.