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Question

Diethyl ether can be decomposed with:

A
HI
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B
KMnO4
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C
NaOH
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D
H2O
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Solution

The correct option is B HI

On heating with concentrated Hydrogen iodide (HI) the C-O bond in ethers breaks forming alcohol and alkyl iodide. For example,

C2H5OC2H5+HIC2H5I+C2H5OH

On boiling with excess of concentrated Hydrogen iodide (HI), Alkyl iodide is formed.

C2H5OC2H5+2HI2C2H5I+H2O


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