Difference between primary and daughters secondary valency
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Solution
The primary valencies indicate the oxidation state of the central metal atom while the secondary valency indicate about the co-ordination number of the metal atom.
Primary valencies are ionizable whereas secondary valencies non-ionizable.
Primary valencies are satisfied by Negative ions while secondary ions are satisfed by neutral or -ve groups.
In complexes, the ligands are projected in space about the central metal atom to give a specific shape to the complex.