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Byju's Answer
Standard XII
Chemistry
Maxwell's Distribution of Speeds
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Question
Give the dimensional formula for Boltzmann’s constant.
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Solution
Boltzmann's constant:
Boltzmann constant is a proportionality constant that connects the average kinetic energy of a system with its absolute temperature.
The exact value of the Boltzmann constant is
1
.
380649
×
10
-
23
m
2
k
g
s
-
2
K
-
1
.
For example, for an ideal gas
m
v
2
2
=
3
2
K
T
, where
m
v
2
2
=
average
kinetic
energy
of
molecule
.
Boltzmann's constant,
k
B
=
2
E
k
3
T
.
The dimensional formula for energy is
m
v
2
2
=
M
1
L
2
T
-
2
as
v
=
L
1
T
-
1
.
k
B
=
2
E
k
3
T
=
M
1
L
2
T
-
2
K
=
M
1
L
2
T
-
2
K
-
1
Hence, the dimensional formula of the Boltzmann constant is
M
1
L
2
T
-
2
K
-
1
,
Here,
M
implies dimension of mass,
L
implies length,
T
implies time,
K
implies temperature.
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The dimensional formula for molar thermal capacity is same that of- (i)gas constant (ii)stefan's constant (iii)Boltzmann constant (iv)specific heat give brief explanation
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