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Problem Solving

Ag 2 S O 4 gi...

Question

${A g}_{2} S O_{4}$ gives white ppt with hypo changing to black after sometime. Black ppt is of

{A g}_{2} S_{2} O_{3}

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{A g}_{2} S O_{4}

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{A g}_{2} S_{4} O_{6}

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{A g}_{2} S

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Solution

The correct option is B ${A g}_{2} S$
The black ppt is due to formation of $A g_{2} S$
$N a_{2} S_{2} O_{3} + 2 A g N O_{3} \to A g_{2} S_{2} O_{3} w h i t e w a t e r - -- \to A g_{2} S b l a c k + H_{2} S O_{4}$

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