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Question

K2Cr2O7+conc.H2SO4+H2O2+ether blue perchromic anhydride (in ethereal layer). Blue colour is due to :

A
CrO3
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B
H2CrO4
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C
H2Cr2O3
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D
CrO5
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Solution

The correct option is D CrO5
The blue colour is due to formation of chromic diperoxide (CrO5)
2H++Cr2O27+4H2O22CrO5chromicdiperoxide(blue)+5H2O

Option D is correct.

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