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Question

KMnO4 oxidizes XOn+ ion to X3 ion, itself changing to Mn2+ in acid medium. 2.68×103 mole of Xn+requires 1.61×103 mole of MnO4. If the weight of 1g equivalent of XCIn is 56, then the atomic mass of X is :

A
41
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B
42
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C
43
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D
44
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Solution

The correct option is A 41
KMnO4 + X+nXO3+Mn+2
1.61×103 moles of MnO4 reacts with 2.63×103 moles of X+n
No. of Equivalents of KMnO4= No. of Equivalents ofX+n
1.61×103×5=2.63×103×(5n)
n=256=M2+35.5 M=41 g

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