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Question

...Na3PO4(aq)+...Mg(NO3)2(aq)...Mg3(PO4)2(s)+...NaNO3(aq)
Equal volumes of 0.10 M sodium phosphate and 0.10 M magnesium nitrate are mixed in a container according to the above unbalanced reaction equation. Which of the following statements is true regarding the reaction?

A
When the reaction is complete, the concentrations of both magnesium and phosphate are essentially 0.
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B
Magnesium nitrate is the limiting reactant.
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C
Sodium phosphate is the limiting reactant.
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D
Since nitrate ion is a spectator ion, the concentration of nitrate ion in the final solution will be the same as in the original magnesium nitrate solution.
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E
Na3PO4 and Mg(NO3)2 react in a 1:1 ratio.
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Solution

The correct option is A Magnesium nitrate is the limiting reactant.
The unbalanced chemical reaction is
Na3PO4(aq)+Mg(NO3)2(aq)Mg3(PO4)2(s)+NaNO3(aq)
The balanced chemical equation is
2Na3PO4(aq)+3Mg(NO3)2(aq)Mg3(PO4)2(s)+6NaNO3(aq)
Equal volumes of 0.10 M sodium phosphate and 0.10 M magnesium nitrate are mixed in a container. This corresponds to equal number of moles of both species.
From the balanced chemical equation, we can see that 3 moles of magnesium nitrate reacts with 2 moles of sodium phosphate. However only 2 moles of magnesium nitrate will be present for 2 moles of sodium phosphate.
Hence, Magnesium nitrate is the limiting reactant and sodium phosphate is the excess reactant.

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