The correct options are
A H2C=CH−Cl
B Ph−Cl
SN1 and SN2 reaction mechanism is not favorable in H2C=CH−Cl and Ph−Cl.
In H2C=CH−Cl, due to presence of carbon carbon double bond, addition reaction is favored over substitution reaction.
In Ph−Cl due to the presence of benzene ring, nucleophilic substitution reaction requires drastic conditions.