Molecularity | Order |
(1) It is the number of reaction species undergoing simultaneous collision. | (1) It is the sum of powers of the concentration terms in the rate law expression. |
(2) It is a theoretical concept. | (2) It is experimentally determined. |
(3) It has integral values only. | (3) It can have fractional values also. |
(4) It cannot be zero. | (4) It can be zero. |
(5) It provides no information on the reaction mechanism. | (5) The slowest step in the reaction can be judged by the order of the reaction & this gives further information about the mechanism. |