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Question

Distinguish between order and molecularity of a reaction.

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Solution

MolecularityOrder
(1) It is the number of reaction species undergoing simultaneous collision.(1) It is the sum of powers of the concentration terms in the rate law expression.
(2) It is a theoretical concept.(2) It is experimentally determined.
(3) It has integral values only.(3) It can have fractional values also.
(4) It cannot be zero.
(4) It can be zero.
(5) It provides no information on the reaction mechanism.(5) The slowest step in the reaction can be judged by the order of the reaction & this gives further information about the mechanism.

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