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Question

Distinguish by adding: Sodium hydroxide solution and ammonium hydroxide solution to
(c) Copper salt solution and ferrous salt solution.

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Solution

Sodium hydroxide on reaction with copper salt gives a pale blue precipitate Cu(OH)2 which is insoluble even in excess of NaOH, while with ferrous salt gives a dirty green precipitate Fe(OH)2 which is also insoluble in excess of NaOH.

FeSO4+2NaOHFe(OH)2+Na2SO4

CuSO4+2NaOHCu(OH)2+2NaSO4
  • Ammonium hydroxide on reaction with copper salt gives a pale blue precipitate Cu(OH)2 which is soluble in excess of NH4OH, while with ferrous salt gives a dirty green precipitate Fe(OH)2 which is insoluble in even excess of NH4OH.


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