Why amides and carboxylic acids have higher boiling point?
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Solution
The explanation of higher boiling point of amides or carboxylic acid is explained below:
Carboxylic acid have higher boiling point than rest of the organic compounds of comparable molecular weight because of the presence of - Bonding.
The formation of dimer through - Bonding makes them one of the most stable and least volatile organic compound
Amides also have the high boiling point of all the acidic derivatives. The reason is again due to -bonding between the Oxygen atom of the amide and the hydrogen atom of the other amide.
Therefore, the explanation of higher boiling point of amides is explained in above points.