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Question

Why amides and carboxylic acids have higher boiling point?


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Solution

The explanation of higher boiling point of amides or carboxylic acid is explained below:

  • Carboxylic acid have higher boiling point than rest of the organic compounds of comparable molecular weight because of the presence of H- Bonding.
  • The formation of dimer through H- Bonding makes them one of the most stable and least volatile organic compound

  • Amides also have the high boiling point of all the acidic derivatives. The reason is again due to H-bonding between the Oxygen atom of the amide and the hydrogen atom of the other amide.

  • Therefore, the explanation of higher boiling point of amides is explained in above points.

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