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Standard XII
Chemistry
Isomerism in Coordination Compounds
Do ketones sh...
Question
Do ketones show metamerism?
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Solution
Metamerism:
Metamerism is a type of isomerism shown by the compounds that have different alkyl groups attached to the same functional group.
Ketones are functional groups having a carbonyl group
-
CO
attached to two alkyl groups
-
R
.
Alkyl groups attached to the carbonyl group can be the same or different.
For example:
are metamers of a ketone named pentanone.
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Compounds A and B are functional isomers. 'A' exhibits metamerism while 'B' does not. The preceding homologues of 'A' do not have metamers. When 'B' is heated with ammoniacal silver nitrate, shining silver mirror is formed along the inner walls of the test tube. Identify A and B and justify.
A is diethyl ketone and B is an aldehyde.
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Prove that the minimum number of carbon atoms in ketone to show metamerism is 5.
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