Draw all the isomers geometrical and optical of-i - CoCl 2 en 2-ii - Co NH 3 Cl en 2-2-iii - Co NH 32 Cl 2 en -

(i) [CoCl2(en)2]+ In total, three isomers are possible. (ii) [Co(NH3)Cl(en)2]2+ Trans isomers are optically inactive. Cis isomers are optically active. (iii ...

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Byju's Answer

Standard XII

Chemistry

Chiral Centres and Chirality

Draw all the ...

Question

Draw all the isomers (geometrical and optical) of:

(i) [CoCl₂(en)₂]⁺

(ii) [Co(NH₃)Cl(en)₂]²⁺

(iii) [Co(NH₃)₂Cl₂(en)]⁺

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Solution

(i) [CoCl₂(en)₂]⁺

In total, three isomers are possible.

(ii) [Co(NH₃)Cl(en)₂]²⁺

Trans-isomers are optically inactive.

Cis-isomers are optically active.

(iii) [Co(NH₃)₂Cl₂(en)]⁺

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Draw all the isomers (geometrical and optical) of: (i) [CoCl2(en)2]+ (ii) [Co(NH3)Cl(en)2]2+ (iii) [Co(NH3)2Cl2(en)]+

(i) [CoCl2(en)2]+ In total, three isomers are possible. (ii) [Co(NH3)Cl(en)2]2+ Trans-isomers are optically inactive. Cis-isomers are optically active. (iii) [Co(NH3)2Cl2(en)]+

Draw all the isomers (geometrical and optical) of:

(i) [CoCl₂(en)₂]⁺

(ii) [Co(NH₃)Cl(en)₂]²⁺

(iii) [Co(NH₃)₂Cl₂(en)]⁺

(i) [CoCl₂(en)₂]⁺

In total, three isomers are possible.

(ii) [Co(NH₃)Cl(en)₂]²⁺

Trans-isomers are optically inactive.

Cis-isomers are optically active.

(iii) [Co(NH₃)₂Cl₂(en)]⁺