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Nomenclature of Coordination Compounds

Draw cis and ...

Question

Draw cis and trans isomers of $[C o C l_{2} (N H_{3})_{4}] C l$ .

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Solution

The given coordination compound show cis and trans geometrical isomerism.

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[C o C l_{2} (N H_{3})_{4}]^{+} + C l^{-} \to [C o C l_{3} (N H_{3})_{3}] + N H_{3}

In the reaction only one isomer of complex product is obtained. The initial complex is

Q. The isomer(s) of

[C o (N H_{3})_{4} C l_{2}]

that has/ have a

C l - C o - C l

90^{\circ}

Q. Give the IUPAC name of

[T i (H_{2} O)_{6}]^{3 +}

. Draw cis and trans isomers of

[P t (N H_{3})_{2} C l_{2}]

[C o (N H_{3}) C l (e n)_{2}]^{2 +}

shows two geometrical isomers cis and trans. Which of the following statements is correct?

Q. What are cis and trans isomers?

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