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Question

Draw the structural isomer of [Co(NH3)5NO2]Cl2 and name the type of isomerism?

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Solution

The structural isomer of [Co(NH3)5NO2]Cl2 is [Co(NH3)5Cl]Cl.NO2
Type of isomerism is ionisation isomerism.
In ionisation isomerism, there is an exchange of ions inside and outside the coordination sphere. Ionisation isomers have same formula but produce different ions in solution.

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