Draw the structure of the following:
a. ${S F}_{4}$
b. $H_{2} S_{2} O_{7}$
c. $H_{2} S_{2} O_{8}$

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Solution

(a) $S F_{4}$ : (Refer to Image 1) : Trigonal pyramidal shape. A sea saw shaped molecule.
(b) $H_{2} S_{2} O_{7}$ : (Refer to Image 2)
(c) $H_{2} S_{2} O_{8}$ : (Refer to Image 3)

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Q. Out of

H_{2} S_{2} O_{3}

H_{2} S_{2} O_{4}

H_{2} S O_{5}

and

H_{2} S_{2} O_{8}

peroxy acids are:

Out of $H_{2} S O_{4} (I), H_{2} S_{2} O_{7} (I I), H_{2} S O_{5} (I I I)$ and $H_{2} S_{2} O_{3} (I V)$ :

Q. What is the oxidation number of sulphur in

H_{2} S_{2} O_{8}

Column-I-Compound, Column-II-Oxidation state, Column-III-Type of linkage

$\begin{matrix} C o l u m n 1 & C o l u m n 2 & C o l u m n 3 (I) & N a_{2} S_{2} O_{3} & (i) & + 5 & (P) & S - O - S (I I) & N a_{2} S_{4} O_{6} & (i i) & - 2 & (Q) & S - S (I I I) & H_{2} S_{2} O_{7} & (i i i) & + 6 & (R) & - (O - O) - (I V) & H_{2} S_{2} O_{8} & (i v) & + 4 & (S) & S = S \end{matrix}$

The only correct combination for Marshall’s acid:

Q. The total number of diprotic acids among the following is:

H_{3} {P O}_{4}, H_{2} {S O}_{4}, H_{3} {P O}_{3}, H_{2} {C O}_{3}, H_{2} S_{2} O_{7}, H_{3} B O_{3}, H_{3} {P O}_{2}, H_{2} {C r O}_{4}, H_{2} {S O}_{3}

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Draw the structure of the following:a.SF4b. H2S2O7c.H2S2O8

(a) SF4: (Refer to Image 1) : Trigonal pyramidal shape. A sea saw shaped molecule.(b) H2S2O7: (Refer to Image 2) (c) H2S2O8: (Refer to Image 3)

Draw the structure of the following:
a. ${S F}_{4}$
b. $H_{2} S_{2} O_{7}$
c. $H_{2} S_{2} O_{8}$

(a) $S F_{4}$ : (Refer to Image 1) : Trigonal pyramidal shape. A sea saw shaped molecule.
(b) $H_{2} S_{2} O_{7}$ : (Refer to Image 2)
(c) $H_{2} S_{2} O_{8}$ : (Refer to Image 3)