Draw the structures of compounds A- B and C- C2H5 3N-CCl2- A An unstable adduct A- B-C2H4 BC

In the first reaction, dichlorocarbene adds to triethylamine #10;to form an unstable adduct A. #10; #10;In the second step, this unstable adduct loses a m ...

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Byju's Answer

Standard XII

Chemistry

Oxidation of Alkynes

Draw the stru...

Question

Draw the structures of compounds $A, B$ and $C$ .
${(C_{2} H_{5})}_{3} N : + : C C l_{2} \to A$ (An unstable adduct)
$A \to B + C_{2} H_{4}$
$B H_{2} O - - \to C$

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Solution

In the first reaction, dichlorocarbene adds to triethylamine to form an unstable adduct A.

In the second step, this unstable adduct loses a molecule of ethylene to form product B. The hydrolysis of product B gives product C. In this step, the dichloro methyl group is hydrolyzed to aldehyde group.

The structures of compounds A to C are as follows:

${(C_{2} H_{5})}_{3} N : + : C C l_{2} \to E t_{3} N^{+} C C l_{2}^{-} A$ (An unstable adduct)

$E t_{3} N^{+} C C l_{2}^{-} A \to E t_{2} N C H C l_{2} B + C_{2} H_{4}$

$E t_{2} N C H C l_{2} B H_{2} O - - \to E t_{2} N - C H O C$

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Draw the structures of compounds A, B and C.(C2H5)3N:+:CCl2→A (An unstable adduct)A→B+C2H4BH2O−−→C

Draw the structures of compounds $A, B$ and $C$ .
${(C_{2} H_{5})}_{3} N : + : C C l_{2} \to A$ (An unstable adduct)
$A \to B + C_{2} H_{4}$
$B H_{2} O - - \to C$