Dry air was passed successively through a solution of 5 g of the solute in 180 g of water and then through pure water. The loss in the weight of solution was 2.50 g and that of pure solvent 0.04 g. The molecular weight of the solute is
A
31.25
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B
3.125
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C
312.5
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D
None
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Solution
The correct option is A 31.25 P∘−PS∝ loss in weight of water chamber and PS∝ loss in weight of solution chamber. p∘−pSpS=n2n1=W2×Mw1Mw2×W1 or 0.042.50=5×18Mw2×180 ∴Mw2=31.25