During electrolysis of aqueous solution of a salt pH in the space near one of the electrodes is increased. Which of the following salt solution was electrolysed?
KCl
When KCl is electrolysed, hydrogen gas is formed at the cathode:
2H++2e−→H2
Since concentration of H+ ions decreases, the pH increases.
Copper is below hydrogen in the activity series. In the other cases copper metal is formed over hydrogen gas being released.