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Question

During the chlor-alkali process, which gas is liberated​ at anode and cathode, respectively?

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Solution

Caustic soda is prepared from common salt through a process called the Chlor-alkali process.
Electrolysis of brine yields:
  • Sodium hydroxide solution at the cathodic side of the solution
  • Chlorine gas at the anode.
  • Hydrogen gas at the cathode.
Reactions involved:
2NaCl(s)+2H2O(l)Cl2(g)+H2(g)+2NaOH (aq)

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