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Question

During the derivation for the work done in isothermal reversible expansion of an ideal gas, the following expression appears.
dW=(PdP)dV=PdV+dPdV

A
True
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B
False
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Solution

The correct option is B False
Derivation of work done in isothermal reversible expansion
dW=P×A×dl=P×dV
The amount of work done by isothermal reversible expansion of an ideal gas from V1 to V2 is
W=V2V1PdV
From ideal gas equation, P=nRTV
Hence W=V2V1nRTVdV=nRTV2V1dVV
On integration we get
W=nRTlnV2V1
Since
P1V1=P2V2P1P2=V2V1W=nRTlnP1P2

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